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Chemistry · THERMODYNAMICS

हिन्दी

At temperature \( T \), the electron gain enthalpy (\( \Delta_{eg}H^\ominus \)) is related to the electron affinity (\( A \)) by which of the following expressions?

  1. A
    \( \Delta_{eg}H^\ominus = -A + \frac{5}{2}RT \)
  2. B
    \( \Delta_{eg}H^\ominus = A - \frac{3}{2}RT \)
  3. C
    \( \Delta_{eg}H^\ominus = -A - \frac{5}{2}RT \)
  4. D
    \( \Delta_{eg}H^\ominus = -A + RT \)
View Answer & Solution

Correct answer · Option C

\( \Delta_{eg}H^\ominus = -A - \frac{5}{2}RT \)

Explanation

For electron gain, \( \Delta_r C_p^\ominus = -\frac{5}{2}R \), hence \( \Delta_{eg}H^\ominus = -A - \frac{5}{2}RT \).
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