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Chemistry · CHEMICAL BONDING AND MOLECULAR STRUCTURE

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Based on the provided diagram depicting covalent and van der Waals radii of chlorine, which statement correctly describes the relation between \( r_c \) and \( r_{\text{vdw}} \)?

Question diagram
  1. A
    \( r_{\text{vdw}} \) is measured between bonded atoms of the same molecule and is smaller than \( r_c \).
  2. B
    \( r_c \) is \( 180\text{ pm} \) and \( r_{\text{vdw}} \) is \( 99\text{ pm} \).
  3. C
    \( r_c \) is half the distance between two similar atoms joined by a covalent bond, whereas \( r_{\text{vdw}} \) includes the nonbonded valence shell.
  4. D
    The internuclear distance between two non-bonded chlorine atoms of adjacent molecules is \( 198\text{ pm} \).
View Answer & Solution

Correct answer · Option C

\( r_c \) is half the distance between two similar atoms joined by a covalent bond, whereas \( r_{\text{vdw}} \) includes the nonbonded valence shell.

Explanation

Covalent radius is half the bonded internuclear distance (99 pm), whereas van der Waals radius (180 pm) represents the overall size including non-bonded valence shells.
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