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Chemistry · THERMODYNAMICS

हिन्दी

Consider the following thermochemical reactions: (i) \( \text{C}(\text{graphite}) + \text{O}_2(g) \rightarrow \text{CO}_2(g) \); \( \Delta_r H^\ominus = -393.5\text{ kJ mol}^{-1} \) (ii) \( \text{CO}(g) + \frac{1}{2}\text{O}_2(g) \rightarrow \text{CO}_2(g) \); \( \Delta_r H^\ominus = -283.0\text{ kJ mol}^{-1} \) Applying Hess's law, the standard enthalpy of formation of \( \text{CO}(g) \) is:

  1. A
    +110.5 kJ mol⁻¹
  2. B
    -110.5 kJ mol⁻¹
  3. C
    +676.5 kJ mol⁻¹
  4. D
    -676.5 kJ mol⁻¹
View Answer & Solution

Correct answer · Option B

-110.5 kJ mol⁻¹

Explanation

Target reaction: \( \text{C}(\text{graphite}) + \frac{1}{2}\text{O}_2(g) \rightarrow \text{CO}(g) \). Subtracting reaction (ii) from (i): \( \Delta_f H^\ominus[\text{CO}(g)] = -393.5 - (-283.0) = -110.5\text{ kJ mol}^{-1} \).
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