Chemistry · PYQ NEET UG 2016(1)
हिन्दी Consider the molecules \( \mathrm{CH}_{4} \), \( \mathrm{NH}_{3} \) and \( \mathrm{H}_{2}\mathrm{O} \). Which of the given statements is FALSE?
- A
The \( \mathrm{H}-\mathrm{O}-\mathrm{H} \) bond angle in \( \mathrm{H}_{2}\mathrm{O} \) is smaller than the \( \mathrm{H}-\mathrm{N}-\mathrm{H} \) bond angle in \( \mathrm{NH}_{3} \).
- B
The \( \mathrm{H}-\mathrm{C}-\mathrm{H} \) bond angle in \( \mathrm{CH}_{4} \) is larger than the \( \mathrm{H}-\mathrm{N}-\mathrm{H} \) bond angle in \( \mathrm{NH}_{3} \).
- C
The \( \mathrm{H}-\mathrm{C}-\mathrm{H} \) bond angle in \( \mathrm{CH}_{4} \), the \( \mathrm{H}-\mathrm{N}-\mathrm{H} \) bond angle in \( \mathrm{NH}_{3} \), and the \( \mathrm{H}-\mathrm{O}-\mathrm{H} \) bond angle in \( \mathrm{H}_{2}\mathrm{O} \) are all greater than \( 90^\circ \).
- D
The \( \mathrm{H}-\mathrm{O}-\mathrm{H} \) bond angle in \( \mathrm{H}_{2}\mathrm{O} \) is larger than the \( \mathrm{H}-\mathrm{C}-\mathrm{H} \) bond angle in \( \mathrm{CH}_{4} \).
View Answer & Solution
Correct answer · Option D
The \( \mathrm{H}-\mathrm{O}-\mathrm{H} \) bond angle in \( \mathrm{H}_{2}\mathrm{O} \) is larger than the \( \mathrm{H}-\mathrm{C}-\mathrm{H} \) bond angle in \( \mathrm{CH}_{4} \).
Explanation
Bond angles are \( \mathrm{CH}_{4} (109.5^\circ) \), \( \mathrm{NH}_{3} (107^\circ) \), and \( \mathrm{H}_{2}\mathrm{O} (104.5^\circ) \). Thus, the \( \mathrm{H}-\mathrm{O}-\mathrm{H} \) angle in \( \mathrm{H}_{2}\mathrm{O} \) is smaller than the \( \mathrm{H}-\mathrm{C}-\mathrm{H} \) angle in \( \mathrm{CH}_{4} \), making statement (D) false.