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Chemistry · PYQ NEET UG 2016(1)

हिन्दी

Consider the molecules \( \mathrm{CH}_{4} \), \( \mathrm{NH}_{3} \) and \( \mathrm{H}_{2}\mathrm{O} \). Which of the given statements is FALSE?

  1. A
    The \( \mathrm{H}-\mathrm{O}-\mathrm{H} \) bond angle in \( \mathrm{H}_{2}\mathrm{O} \) is smaller than the \( \mathrm{H}-\mathrm{N}-\mathrm{H} \) bond angle in \( \mathrm{NH}_{3} \).
  2. B
    The \( \mathrm{H}-\mathrm{C}-\mathrm{H} \) bond angle in \( \mathrm{CH}_{4} \) is larger than the \( \mathrm{H}-\mathrm{N}-\mathrm{H} \) bond angle in \( \mathrm{NH}_{3} \).
  3. C
    The \( \mathrm{H}-\mathrm{C}-\mathrm{H} \) bond angle in \( \mathrm{CH}_{4} \), the \( \mathrm{H}-\mathrm{N}-\mathrm{H} \) bond angle in \( \mathrm{NH}_{3} \), and the \( \mathrm{H}-\mathrm{O}-\mathrm{H} \) bond angle in \( \mathrm{H}_{2}\mathrm{O} \) are all greater than \( 90^\circ \).
  4. D
    The \( \mathrm{H}-\mathrm{O}-\mathrm{H} \) bond angle in \( \mathrm{H}_{2}\mathrm{O} \) is larger than the \( \mathrm{H}-\mathrm{C}-\mathrm{H} \) bond angle in \( \mathrm{CH}_{4} \).
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Correct answer · Option D

The \( \mathrm{H}-\mathrm{O}-\mathrm{H} \) bond angle in \( \mathrm{H}_{2}\mathrm{O} \) is larger than the \( \mathrm{H}-\mathrm{C}-\mathrm{H} \) bond angle in \( \mathrm{CH}_{4} \).

Explanation

Bond angles are \( \mathrm{CH}_{4} (109.5^\circ) \), \( \mathrm{NH}_{3} (107^\circ) \), and \( \mathrm{H}_{2}\mathrm{O} (104.5^\circ) \). Thus, the \( \mathrm{H}-\mathrm{O}-\mathrm{H} \) angle in \( \mathrm{H}_{2}\mathrm{O} \) is smaller than the \( \mathrm{H}-\mathrm{C}-\mathrm{H} \) angle in \( \mathrm{CH}_{4} \), making statement (D) false.
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