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Chemistry · THERMODYNAMICS

हिन्दी

Which of the following substances has a standard molar enthalpy of formation (\( \Delta_f H^\ominus \)) equal to zero at 298 K and 1 bar by convention?

  1. \( \text{C}(\text{graphite}) \)
  2. \( \text{Br}_2(g) \)
  3. \( \text{H}_2\text{O}(l) \)
  4. \( \text{C}(\text{diamond}) \)

Correct answer · Option 1

\( \text{C}(\text{graphite}) \)

Explanation

Graphite is the thermodynamically most stable reference form of elemental carbon at 298 K and 1 bar, so its \( \Delta_f H^\ominus = 0 \), whereas diamond has \( \Delta_f H^\ominus = +1.89\text{ kJ mol}^{-1} \).
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