Chemistry · PYQ NEET UG 2017
हिन्दीPredict the CORRECT intermediate and product in the following reaction: \( \text{H}_3\text{C}-\text{C}\equiv\text{CH} \xrightarrow{\text{H}_2\text{O, H}_2\text{SO}_4}{\text{HgSO}_4} \text{ Intermediate (A)} \rightarrow \text{Product (B)} \)
Correct answer · Option 4
A : \( \text{H}_3\text{C}-\text{C}=\text{CH}_2 \) with \( \text{OH} \) attached, B : \( \text{H}_3\text{C}-\text{C}-\text{CH}_3 \) with =O
Explanation
Hydration of propyne yields an enol intermediate (A: \( \text{H}_3\text{C}-\text{C(OH)}=\text{CH}_2 \)), which tautomerizes to acetone as product (B: \( \text{H}_3\text{C}-\text{CO}-\text{CH}_3 \)).