Chemistry · EQUILIBRIUM
हिन्दीIn the equilibrium \( \text{Fe}^{3+}(\text{aq}) + \text{SCN}^-(\text{aq}) \rightleftharpoons [\text{Fe}(\text{SCN})]^{2+}(\text{aq}) \) (deep red), what happens to the red colour intensity upon the addition of oxalic acid \( (\text{H}_2\text{C}_2\text{O}_4) \) and why?
Correct answer · Option 4
Red colour intensity decreases because it forms a stable complex \( [\text{Fe}(\text{C}_2\text{O}_4)_3]^{3-} \), removing free \( \text{Fe}^{3+} \) ions
Explanation
Oxalic acid reacts with \( \text{Fe}^{3+} \) to form the stable complex \( [\text{Fe}(\text{C}_2\text{O}_4)_3]^{3-} \), decreasing free \( \text{Fe}^{3+} \) concentration and shifting equilibrium to the left, decreasing red colour.