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Chemistry · THERMODYNAMICS

हिन्दी

For the formation reaction \( \text{H}_2(g) + \text{Br}_2(l) \to 2\text{HBr}(g) \), the reaction enthalpy is \( \Delta_r H^\ominus = -72.8\text{ kJ mol}^{-1} \). What is the standard molar enthalpy of formation (\( \Delta_f H^\ominus \)) of \( \text{HBr}(g) \)?

  1. \( +36.4\text{ kJ mol}^{-1} \)
  2. \( -72.8\text{ kJ mol}^{-1} \)
  3. \( -36.4\text{ kJ mol}^{-1} \)
  4. \( -145.6\text{ kJ mol}^{-1} \)

Correct answer · Option 3

\( -36.4\text{ kJ mol}^{-1} \)

Explanation

Standard enthalpy of formation is defined for the formation of 1 mole of compound from its elements. Since 2 moles of HBr are formed, \( \Delta_f H^\ominus(\text{HBr}) = \frac{\Delta_r H^\ominus}{2} = \frac{-72.8}{2} = -36.4\text{ kJ mol}^{-1} \).
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