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Chemistry · THERMODYNAMICS

हिन्दी

Why is the absolute value of internal energy (\( U \)) of a system impossible to determine, whereas the change in internal energy (\( \Delta U \)) is readily measurable?

  1. Because internal energy is zero for all real substances at absolute zero temperature according to the first law.
  2. Because internal energy is a path-dependent quantity that varies with the rate of measuring apparatus.
  3. Because internal energy includes translational, rotational, vibrational, electronic, and nuclear energies, whose absolute sum cannot be evaluated, but changes during physical/chemical processes can be quantified via heat and work.
  4. Because internal energy changes continuously even when a system is completely isolated from the universe.

Correct answer · Option 3

Because internal energy includes translational, rotational, vibrational, electronic, and nuclear energies, whose absolute sum cannot be evaluated, but changes during physical/chemical processes can be quantified via heat and work.

Explanation

Internal energy represents the sum of all microscopic forms of energy (chemical, electrical, mechanical, molecular) which cannot be known absolutely; however, \( \Delta U = q + w \) can be precisely measured experimentally.
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