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Chemistry · EQUILIBRIUM

हिन्दी

In the heterogeneous equilibrium \( \text{Ni}(\text{s}) + 4\text{CO}(\text{g}) \rightleftharpoons \text{Ni}(\text{CO})_4(\text{g}) \), which expression represents the equilibrium constant \( K_c \)?

  1. \( \frac{[\text{Ni}(\text{CO})_4]}{[\text{Ni}][\text{CO}]^4} \)
  2. \( \frac{[\text{Ni}(\text{CO})_4]}{[\text{CO}]} \)
  3. \( \frac{[\text{CO}]^4}{[\text{Ni}(\text{CO})_4]} \)
  4. \( \frac{[\text{Ni}(\text{CO})_4]}{[\text{CO}]^4} \)

Correct answer · Option 4

\( \frac{[\text{Ni}(\text{CO})_4]}{[\text{CO}]^4} \)

Explanation

The molar concentration of a pure solid like Ni(s) is constant and is incorporated into the equilibrium constant, giving \( K_c = \frac{[\text{Ni}(\text{CO})_4]}{[\text{CO}]^4} \).
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