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Chemistry · THERMODYNAMICS

हिन्दी

Which of the following conditions represents the exact state where \( \Delta H = \Delta U \) for a chemical reaction involving gases?

  1. A
    The reaction is conducted at extremely high pressures so that ideal behavior is severely departed from.
  2. B
    The reaction occurs in an open vessel at constant external atmospheric pressure.
  3. C
    The reaction is highly exothermic such that \( q_p < 0 \).
  4. D
    The difference between the number of moles of gaseous products and gaseous reactants (\( \Delta n_g \)) is identically zero.
View Answer & Solution

Correct answer · Option D

The difference between the number of moles of gaseous products and gaseous reactants (\( \Delta n_g \)) is identically zero.

Explanation

Since \( \Delta H = \Delta U + \Delta n_g RT \), when \( \Delta n_g = 0 \), the term \( \Delta n_g RT = 0 \), leading strictly to \( \Delta H = \Delta U \).
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