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Chemistry · EQUILIBRIUM

हिन्दी

Consider the following statements regarding the ionization of weak acids and bases: (A) Larger value of \( K_a \) indicates a stronger acid. (B) For a weak acid \( \text{HX} \), \( K_a = \frac{c\alpha^2}{1-\alpha} \), where \( \alpha \) is the degree of ionization. (C) As the initial concentration \( c \) of a weak acid decreases, its degree of ionization \( \alpha \) also decreases. (D) At 298 K, the ionization constant \( K_b \) of ammonia is \( 1.77 \times 10^{-5} \). Which of the above statements are correct?

  1. (A), (B), (C) and (D)
  2. (A), (B) and (D) only
  3. (A) and (C) only
  4. (B) and (C) only

Correct answer · Option 2

(A), (B) and (D) only

Explanation

(A), (B), and (D) are correct. (C) is incorrect because by Ostwald's dilution law, the degree of ionization \( \alpha \approx \sqrt{K_a/c} \) increases upon dilution (decreasing concentration).
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