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Chemistry · PYQ NEET UG 2021

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Match List-I with List-II: List-I List-II i \( \text{C}_6\text{H}_6 \xrightarrow[\text{Anhyd. }\text{AlCl}_3]{\text{CO, HCl}} \text{C}_6\text{H}_5\text{CHO} \) a Hell-Volhard-Zelinsky reaction ii \( \text{R} - \text{C} - \text{CH}_3 + \text{NaOX} \longrightarrow \text{R} - \text{CH}_2 - \text{OH} + \text{R}'\text{COOH} \) b Gattermann-Koch reaction iii \( \text{R} - \text{CH}_2 - \text{OH} + \text{R}'\text{COOH} \xrightarrow{\text{Conc. H}_2\text{SO}_4} \text{Ester} \) c Haloform reaction iv \( \text{R} - \text{CH}_2\text{COOH} \xrightarrow[\text{(ii) }\text{H}_2\text{O}]{\text{(i) X}_2/\text{Red P}} \text{R} - \text{CH(X)}\text{COOH} \) d Esterification Choose the CORRECT answer from the options given below.

Match List-I with List-II:

List-I List-II
i \( \text{C}_6\text{H}_6 \xrightarrow[\text{Anhyd. }\text{AlCl}_3]{\text{CO, HCl}} \text{C}_6\text{H}_5\text{CHO} \) a Hell-Volhard-Zelinsky reaction
ii \( \text{R} - \text{C} - \text{CH}_3 + \text{NaOX} \longrightarrow \text{R} - \text{CH}_2 - \text{OH} + \text{R}'\text{COOH} \) b Gattermann-Koch reaction
iii \( \text{R} - \text{CH}_2 - \text{OH} + \text{R}'\text{COOH} \xrightarrow{\text{Conc. H}_2\text{SO}_4} \text{Ester} \) c Haloform reaction
iv \( \text{R} - \text{CH}_2\text{COOH} \xrightarrow[\text{(ii) }\text{H}_2\text{O}]{\text{(i) X}_2/\text{Red P}} \text{R} - \text{CH(X)}\text{COOH} \) d Esterification

Choose the CORRECT answer from the options given below.

  1. i – c, ii – b, iii – a, iv – d
  2. i – a, ii – d, iii – c, iv – b
  3. i – b, ii – c, iii – d, iv – a
  4. i – d, ii – a, iii – b, iv – c

Correct answer · Option 3

i – b, ii – c, iii – d, iv – a

Explanation

Reaction (i) is Gattermann-Koch (b), (ii) is Haloform (c), (iii) is Esterification (d), and (iv) is Hell-Volhard-Zelinsky (a). Hence, i-b, ii-c, iii-d, iv-a.
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