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Chemistry · PYQ NEET UG 2018

हिन्दी

The compound A on treatment with Na gives B, and with \( \mathrm{PCl_5} \) gives C. B and C react together to give diethyl ether. A, B and C are in the order of

  1. \( \mathrm{C_2H_5OH, C_2H_6, C_2H_5Cl} \)
  2. \( \mathrm{C_2H_5OH, C_2H_5Cl, C_2H_5ONa} \)
  3. \( \mathrm{C_5H_5Cl, C_2H_6, C_2H_5OH} \)
  4. \( \mathrm{C_2H_5OH, C_2H_5ONa, C_2H_5Cl} \)

Correct answer · Option 4

\( \mathrm{C_2H_5OH, C_2H_5ONa, C_2H_5Cl} \)

Explanation

A is \( \mathrm{C_2H_5OH} \). With Na, it forms B \( (\mathrm{C_2H_5ONa}) \). With \( \mathrm{PCl_5} \), it forms C \( (\mathrm{C_2H_5Cl}) \). Williamson synthesis between B and C yields diethyl ether.
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