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Chemistry · PYQ NEET UG 2018

हिन्दी

The geometry and magnetic behaviour of the complex \( [\mathrm{Ni}(\mathrm{CO})_{4}] \) are

  1. square planar geometry and diamagnetic
  2. tetrahedral geometry and diamagnetic
  3. square planar geometry and paramagnetic
  4. tetrahedral geometry and paramagnetic

Correct answer · Option 2

tetrahedral geometry and diamagnetic

Explanation

In \( [\mathrm{Ni}(\mathrm{CO})_4] \), Ni has \( \mathrm{sp}^3 \) hybridization due to strong field CO ligands forcing pairing, resulting in tetrahedral geometry and diamagnetic behavior.
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