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Chemistry · PYQ NEET UG 2021

हिन्दी

Match List-I with List-II: List-I List-II i \( [\mathrm{Fe}(\mathrm{CN})_{6}]^{3-} \) a \( 5.92\text{ BM} \) ii \( [\mathrm{Fe}(\mathrm{H}_{2}\mathrm{O})_{6}]^{3+} \) b \( 0\text{ BM} \) iii \( [\mathrm{Fe}(\mathrm{CN})_{6}]^{4-} \) c \( 4.90\text{ BM} \) iv \( [\mathrm{Fe}(\mathrm{H}_{2}\mathrm{O})_{6}]^{2+} \) d \( 1.73\text{ BM} \) Choose the CORRECT answer from the options given below.

Match List-I with List-II:

List-I List-II
i \( [\mathrm{Fe}(\mathrm{CN})_{6}]^{3-} \) a \( 5.92\text{ BM} \)
ii \( [\mathrm{Fe}(\mathrm{H}_{2}\mathrm{O})_{6}]^{3+} \) b \( 0\text{ BM} \)
iii \( [\mathrm{Fe}(\mathrm{CN})_{6}]^{4-} \) c \( 4.90\text{ BM} \)
iv \( [\mathrm{Fe}(\mathrm{H}_{2}\mathrm{O})_{6}]^{2+} \) d \( 1.73\text{ BM} \)

Choose the CORRECT answer from the options given below.

  1. \( \mathrm{i}-\mathrm{b}, \text{ ii}-\mathrm{d}, \text{ iii}-\mathrm{c}, \text{ iv}-\mathrm{a} \)
  2. \( \mathrm{i}-\mathrm{a}, \text{ ii}-\mathrm{c}, \text{ iii}-\mathrm{d}, \text{ iv}-\mathrm{b} \)
  3. \( \mathrm{i}-\mathrm{d}, \text{ ii}-\mathrm{a}, \text{ iii}-\mathrm{b}, \text{ iv}-\mathrm{c} \)
  4. \( \mathrm{i}-\mathrm{d}, \text{ ii}-\mathrm{b}, \text{ iii}-\mathrm{a}, \text{ iv}-\mathrm{c} \)

Correct answer · Option 3

\( \mathrm{i}-\mathrm{d}, \text{ ii}-\mathrm{a}, \text{ iii}-\mathrm{b}, \text{ iv}-\mathrm{c} \)

Explanation

Calculated magnetic moments from unpaired electrons \( n \): i. \( [\mathrm{Fe}(\mathrm{CN})_{6}]^{3-} \rightarrow n=1 \rightarrow 1.73\text{ BM (d)} \), ii. \( [\mathrm{Fe}(\mathrm{H}_{2}\mathrm{O})_{6}]^{3+} \rightarrow n=5 \rightarrow 5.92\text{ BM (a)} \), iii. \( [\mathrm{Fe}(\mathrm{CN})_{6}]^{4-} \rightarrow n=0 \rightarrow 0\text{ BM (b)} \), iv. \( [\mathrm{Fe}(\mathrm{H}_{2}\mathrm{O})_{6}]^{2+} \rightarrow n=4 \rightarrow 4.90\text{ BM (c)} \).
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