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Chemistry · PYQ NEET UG 2019(2)

हिन्दी

Which of the following statements is CORRECT regarding a solution of two components A and B exhibiting positive deviation from ideal behaviour?

  1. Intermolecular attractive forces between \( A - A \) and \( B - B \) are equal to those between \( A - B \).
  2. Intermolecular attractive forces between \( A - A \) and \( B - B \) are stronger than those between \( A - B \).
  3. \( \Delta_{\text{mix}}H = 0 \) at constant \( T \) and \( P \).
  4. \( \Delta_{\text{mix}}V = 0 \) at constant \( T \) and \( P \).

Correct answer · Option 2

Intermolecular attractive forces between \( A - A \) and \( B - B \) are stronger than those between \( A - B \).

Explanation

In solutions showing positive deviation, solute-solvent \( (A-B) \) interactions are weaker than solute-solute \( (A-A) \) and solvent-solvent \( (B-B) \) interactions, leading to expansion in volume and absorption of heat.
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