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Chemistry · CHEMICAL BONDING AND MOLECULAR STRUCTURE

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For a molecule of type \( \text{AB}_5 \) having no lone pairs on the central atom (such as \( \text{PCl}_5 \)), the molecular geometry and the bond angles present are:

  1. Square pyramidal; \( 90^\circ \) only
  2. Trigonal bipyramidal; \( 120^\circ \) and \( 90^\circ \)
  3. Pentagonal planar; \( 72^\circ \) only
  4. Octahedral; \( 90^\circ \) and \( 180^\circ \)

Correct answer · Option 2

Trigonal bipyramidal; \( 120^\circ \) and \( 90^\circ \)

Explanation

\( \text{AB}_5 \) with 5 electron pairs and no lone pair forms a trigonal bipyramidal geometry with bond angles of \( 120^\circ \) (equatorial) and \( 90^\circ \) (axial-equatorial).
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