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Chemistry · PYQ NEET UG 2016(1)

हिन्दी

In which of the following options the order of arrangement does not agree with the variation of property indicate against it?

  1. A
    \( \mathrm{I} < \mathrm{Br} < \mathrm{Cl} < \mathrm{F} \) (increasing electron gain enthalpy)
  2. B
    \( \mathrm{B} < \mathrm{C} < \mathrm{N} < \mathrm{O} \) (increasing first ionisation enthalpy)
  3. C
    \( \mathrm{Li} < \mathrm{Na} < \mathrm{K} < \mathrm{Rb} \) (increasing metallic radius)
  4. D
    \( \mathrm{Al}^{3+} > \mathrm{Mg}^{2+} < \mathrm{Na}^+ < \mathrm{F}^- \) (increasing ionic size)

Correct answer · Option B

\( \mathrm{B} < \mathrm{C} < \mathrm{N} < \mathrm{O} \) (increasing first ionisation enthalpy)

Explanation

For first ionisation enthalpy, \( \mathrm{N} \) has a higher value than \( \mathrm{O} \) due to its stable half-filled \( 2p^3 \) configuration. Thus the order \( \mathrm{B} < \mathrm{C} < \mathrm{N} < \mathrm{O} \) is incorrect because \( \mathrm{N} > \mathrm{O} \).
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