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Chemistry · THERMODYNAMICS

हिन्दी

For an ideal gas, the difference between molar heat capacity at constant pressure and at constant volume is given by \( C_p - C_v = R \). This relationship is derived using the relation:

  1. \( \Delta H = \Delta U - \Delta(pV) \)
  2. \( \Delta H = \Delta U + \Delta(pV) \)
  3. \( \Delta H = q_v + w \)
  4. \( q_p = q_v - R\Delta T \)

Correct answer · Option 2

\( \Delta H = \Delta U + \Delta(pV) \)

Explanation

By definition, \( \Delta H = \Delta U + \Delta(pV) \). For 1 mole of an ideal gas, \( pV = RT \), so \( \Delta H = \Delta U + R\Delta T \), leading to \( C_p\Delta T = C_v\Delta T + R\Delta T \), hence \( C_p - C_v = R \).
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