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Chemistry · EQUILIBRIUM

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Which of the following orders of acid strength is correct and aligned with the combined influence of H–A bond dissociation energy and electronegativity?

  1. \( \text{HI} < \text{HBr} < \text{HCl} < \text{HF} \)
  2. \( \text{H}_2\text{O} < \text{H}_2\text{S} < \text{CH}_4 < \text{NH}_3 \)
  3. \( \text{CH}_4 < \text{NH}_3 < \text{H}_2\text{O} < \text{HF} \)
  4. \( \text{HF} < \text{H}_2\text{O} < \text{NH}_3 < \text{CH}_4 \)

Correct answer · Option 3

\( \text{CH}_4 < \text{NH}_3 < \text{H}_2\text{O} < \text{HF} \)

Explanation

Across a period (from carbon to fluorine), electronegativity increases, making the H-A bond progressively more polar and facilitating proton release. Thus, the correct order is \( \text{CH}_4 < \text{NH}_3 < \text{H}_2\text{O} < \text{HF} \).
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