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Chemistry · THERMODYNAMICS

हिन्दी

Consider the following statements regarding the Born-Haber cycle for \( \text{NaCl(s)} \): (A) Sublimation of metallic sodium is an endothermic step. (B) Ionization of gaseous sodium atoms to \( \text{Na}^+(\text{g}) \) is an exothermic step. (C) Dissociation of \( \text{Cl}_2(\text{g}) \) molecules into \( \text{Cl}(\text{g}) \) atoms is an endothermic step. (D) Electron gain by \( \text{Cl}(\text{g}) \) to form \( \text{Cl}^-(\text{g}) \) is an exothermic step. Which of the above statements are correct?

  1. (A) and (B) only
  2. (A), (C) and (D) only
  3. (B), (C) and (D) only
  4. All (A), (B), (C) and (D)

Correct answer · Option 2

(A), (C) and (D) only

Explanation

Ionization of gaseous Na atoms requires energy (\( \Delta_i H^\ominus = +496\text{ kJ mol}^{-1} \)), so (B) is endothermic, not exothermic. (A), (C), and (D) are correct.
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