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Chemistry · PYQ NEET UG 2016(2)

हिन्दी

If the \( \text{E}^\circ_{\text{cell}} \) for a given reaction has a negative value, which of the following gives the CORRECT relationships for the values of \( \Delta \text{G}^\circ \) and \( \text{K}_{\text{eq}} \)?

  1. \( \Delta \text{G}^\circ < 0; \text{K}_{\text{eq}} < 1 \)
  2. \( \Delta \text{G}^\circ > 0; \text{K}_{\text{eq}} < 1 \)
  3. \( \Delta \text{G}^\circ > 0; \text{K}_{\text{eq}} > 1 \)
  4. \( \Delta \text{G}^\circ < 0; \text{K}_{\text{eq}} > 1 \)

Correct answer · Option 2

\( \Delta \text{G}^\circ > 0; \text{K}_{\text{eq}} < 1 \)

Explanation

Since \( \Delta \text{G}^\circ = -nFE^\circ_{\text{cell}} \) and \( \Delta \text{G}^\circ = -RT \ln K_{\text{eq}} \), a negative \( E^\circ_{\text{cell}} \) implies positive \( \Delta G^\circ \) and \( K_{\text{eq}} < 1 \).
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