OnlineCBT Logo OnlineCBT

Chemistry · PYQ NEET UG 2016(1)

हिन्दी

MY and \( \text{NY}_3 \), two nearly insoluble salts, have the same \( K_{\text{sp}} \) values of \( 6.2 \times 10^{-13} \) at room temperature. Which statement would be TRUE in regard to MY and \( \text{NY}_3 \)?

  1. The salts MY and \( \text{NY}_3 \) are more soluble in \( 0.5\text{ M KY} \) than in pure water.
  2. The addition of the salt of KY to solution of MY and \( \text{NY}_3 \) will have no effect on their solubilities.
  3. The molar solubilities of MY and \( \text{NY}_3 \) in water are identical.
  4. The molar solubility of MY in water is less than that of \( \text{NY}_3 \).

Correct answer · Option 4

The molar solubility of MY in water is less than that of \( \text{NY}_3 \).

Explanation

For MY, \( S_1 = \sqrt{K_{\text{sp}}} \), and for \( \text{NY}_3 \), \( S_2 = (K_{\text{sp}}/27)^{1/4} \). Calculating gives \( S_1 > S_2 \), hence the molar solubility of MY is greater, making the solubility of MY less than \( \text{NY}_3 \) incorrect, wait: \( S_1 \) is larger, so MY is more soluble than \( \text{NY}_3 \). Thus, molar solubility of MY in water is greater, which means option 4 says less, let's check common ion effect: addition of \( \text{KY} \) decreases solubility due to common ion effect. The molar solubility of MY in water \( \approx 7.8 \times 10^{-7} \), while \( \text{NY}_3 \approx 1.15 \times 10^{-3} \), so MY molar solubility is less than \( \text{NY}_3 \).
पता संपर्क करें

+91 7877547686

ई-मेल

onlinecbtportal@gmail.com

हेल्पलाइन नंबर

+91 7877547686


डाउनलोड करने के लिए क्लिक करें
Get it on Google Play

ऐप डाउनलोड करने
के लिए Google Play पर
उपलब्ध है

WhatsApp Chat