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Chemistry · PYQ NEET UG 2017

हिन्दी

Pick out the CORRECT statement with respect to \( [\text{Mn(CN)}_6]^{3-} \).

  1. It is \( \text{sp}^3\text{d}^2 \) hybridized and tetrahedral.
  2. It is \( \text{d}^2\text{sp}^3 \) hybridized and octahedral.
  3. It is \( \text{dsp}^2 \) hybridized and square planar.
  4. It is \( \text{sp}^3\text{d}^2 \) hybridized and octahedral.

Correct answer · Option 2

It is \( \text{d}^2\text{sp}^3 \) hybridized and octahedral.

Explanation

In \( [\text{Mn(CN)}_6]^{3-} \), \( \text{Mn}^{3+} \) has \( \text{d}^4 \) configuration. Since \( \text{CN}^- \) is a strong field ligand, pairing occurs, leaving two inner d-orbitals vacant, leading to \( \text{d}^2\text{sp}^3 \) hybridization and octahedral geometry.
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