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Chemistry · PYQ NEET UG 2021

हिन्दी

In which one of the following arrangements the given sequence is NOT strictly according to the properties indicated against it?

  1. \( \mathrm{H}_{2}\mathrm{O} < \mathrm{H}_{2}\mathrm{S} < \mathrm{H}_{2}\mathrm{Se} < \mathrm{H}_{2}\mathrm{Te} \) (Increasing \( \mathrm{pK}_{a} \) values)
  2. \( \mathrm{NH}_{3} < \mathrm{PH}_{3} < \mathrm{AsH}_{3} < \mathrm{SbH}_{3} \) (Increasing acidic character)
  3. \( \mathrm{CO}_{2} < \mathrm{SiO}_{2} < \mathrm{SnO}_{2} < \mathrm{PbO}_{2} \) (Increasing oxidizing power)
  4. \( \mathrm{HF} < \mathrm{HCl} < \mathrm{HBr} < \mathrm{HI} \) (Increasing acidic strength)

Correct answer · Option 1

\( \mathrm{H}_{2}\mathrm{O} < \mathrm{H}_{2}\mathrm{S} < \mathrm{H}_{2}\mathrm{Se} < \mathrm{H}_{2}\mathrm{Te} \) (Increasing \( \mathrm{pK}_{a} \) values)

Explanation

Acidic strength increases with decreasing bond dissociation enthalpy, so \( \mathrm{H}_{2}\mathrm{O} \) is the weakest acid and has the highest \( \mathrm{pK}_{a} \) value, making option (1) incorrect because higher \( \mathrm{pK}_{a} \) means weaker acid.
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