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Chemistry · PYQ NEET UG 2024

हिन्दी

In which of the following equilibria, \( K_p \) and \( K_c \) are NOT equal?

  1. \( CO_{(g)} + H_2O_{(g)} \rightleftharpoons CO_{2(g)} + H_{2(g)} \)
  2. \( 2\text{ BrCl}_{(g)} \rightleftharpoons Br_{2(g)} + Cl_{2(g)} \)
  3. \( PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)} \)
  4. \( H_{2(g)} + I_{2(g)} \rightleftharpoons 2\text{ HI}_{(g)} \)

Correct answer · Option 3

\( PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)} \)

Explanation

For the reaction \( PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)} \), \( \Delta n_g = (1 + 1) - 1 = 1 \neq 0 \). Since \( K_p = K_c(RT)^{\Delta n_g} \), here \( K_p \neq K_c \).
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