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Chemistry · EQUILIBRIUM

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For the gaseous reaction \( \text{N}_2(\text{g}) + 3\text{H}_2(\text{g}) \rightleftharpoons 2\text{NH}_3(\text{g}) \), the equilibrium constant is \( K_c \). If the reaction is written as \( \text{NH}_3(\text{g}) \rightleftharpoons \frac{1}{2}\text{N}_2(\text{g}) + \frac{3}{2}\text{H}_2(\text{g}) \), what is the new equilibrium constant \( K'_c \) in terms of \( K_c \)?

  1. \( (K_c)^{1/2} \)
  2. \( \frac{1}{K_c^2} \)
  3. \( \frac{1}{\sqrt{K_c}} \)
  4. \( \sqrt{2K_c} \)

Correct answer · Option 3

\( \frac{1}{\sqrt{K_c}} \)

Explanation

Reversing the reaction inverts \( K_c \) to \( 1/K_c \), and multiplying coefficients by \( 1/2 \) raises the constant to power \( 1/2 \), giving \( K'_c = (1/K_c)^{1/2} = 1/\sqrt{K_c} \).
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