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Chemistry · Classification of Elements and Periodicity in Properties

हिन्दी

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): The first ionization enthalpy of molecular nitrogen is greater than that of oxygen. Reason (R): Nitrogen has a stable half-filled \( 2p^3 \) electronic configuration which requires higher energy to remove an electron compared to oxygen's \( 2p^4 \) configuration. In the light of the above statements, choose the correct answer from the options given below:

  1. Both (A) and (R) are true and (R) is the correct explanation of (A).
  2. Both (A) and (R) are true but (R) is NOT the correct explanation of (A).
  3. (A) is true but (R) is false.
  4. (A) is false but (R) is true.

Correct answer · Option 1

Both (A) and (R) are true and (R) is the correct explanation of (A).

Explanation

Nitrogen (\( 1s^2 2s^2 2p^3 \)) has extra stability due to its half-filled p-orbitals, leading to a higher ionization enthalpy than oxygen (\( 1s^2 2s^2 2p^4 \)). Thus both Assertion and Reason are true and R correctly explains A.
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