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Chemistry · PYQ NEET UG 2016(1)

हिन्दी

In the reaction, \( \mathrm{H-C \equiv C-H} \xrightarrow[ii. \mathrm{CH}_{3}\mathrm{CH}_{2}\mathrm{Br}]{i. \mathrm{NaNH}_{2} / \text{liq. } \mathrm{NH}_{3}} \mathrm{X} \xrightarrow[ii. \mathrm{CH}_{3}\mathrm{CH}_{2}\mathrm{Br}]{i. \mathrm{NaNH}_{2} / \text{liq. } \mathrm{NH}_{3}} \mathrm{Y} \) X and Y are

  1. \( \mathrm{X = But-1-yne ; Y = Hex-3-yne} \)
  2. \( \mathrm{X = But-1-yne ; Y = Hex-2-yne} \)
  3. \( \mathrm{X = But-2-yne ; Y = Hex-2-yne} \)
  4. \( \mathrm{X = But-2-yne ; Y = Hex-3-yne} \)

Correct answer · Option 1

\( \mathrm{X = But-1-yne ; Y = Hex-3-yne} \)

Explanation

Acetylene reacts with \( \mathrm{NaNH}_{2} \) and \( \mathrm{CH}_{3}\mathrm{CH}_{2}\mathrm{Br} \) to give But-1-yne (X), which upon further alkylation gives Hex-3-yne (Y).
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