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Chemistry · PYQ NEET UG 2019(1)

हिन्दी

The CORRECT order of the basic strength of methyl substituted amines in aqueous solution is ____.

  1. \( (\text{CH}_3)_3\text{N} > \text{CH}_3\text{NH}_2 > (\text{CH}_3)_2\text{NH} \)
  2. \( (\text{CH}_3)_3\text{N} > (\text{CH}_3)_2\text{NH} > \text{CH}_3\text{NH}_2 \)
  3. \( \text{CH}_3\text{NH}_2 > (\text{CH}_3)_2\text{NH} > (\text{CH}_3)_3\text{N} \)
  4. \( (\text{CH}_3)_2\text{NH} > \text{CH}_3\text{NH}_2 > (\text{CH}_3)_3\text{N} \)

Correct answer · Option 4

\( (\text{CH}_3)_2\text{NH} > \text{CH}_3\text{NH}_2 > (\text{CH}_3)_3\text{N} \)

Explanation

In aqueous medium, due to inductive effect, solvation effect and steric hindrance, the basicity order of methylamines is \( 2^\circ > 1^\circ > 3^\circ \), i.e., \( (\text{CH}_3)_2\text{NH} > \text{CH}_3\text{NH}_2 > (\text{CH}_3)_3\text{N} \).
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