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Chemistry · PYQ NEET UG 2016(2)

हिन्दी

Consider the reaction: \( \mathrm{CH}_3\mathrm{CH}_2\mathrm{CH}_2\mathrm{Br} + \mathrm{NaCN} \longrightarrow \mathrm{CH}_3\mathrm{CH}_2\mathrm{CH}_2\mathrm{CN} + \mathrm{NaBr} \) This reaction will be the fastest in ______.

  1. water
  2. ethanol
  3. methanol
  4. N,N'-dimethylformamide (DMF)

Correct answer · Option 4

N,N'-dimethylformamide (DMF)

Explanation

The reaction is an \( \mathrm{S_N}2 \) substitution reaction which proceeds fastest in polar aprotic solvents such as DMF because they do not solvate the nucleophile strongly.
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