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Chemistry · THERMODYNAMICS

हिन्दी

When both \( \Delta_r H^\circ > 0 \) and \( \Delta_r S^\circ > 0 \), what is the sign of \( \Delta_r G^\circ \) and the spontaneity of the reaction at high temperatures?

  1. \( \Delta_r G^\circ < 0 \), spontaneous at high temperature
  2. \( \Delta_r G^\circ > 0 \), nonspontaneous at high temperature
  3. \( \Delta_r G^\circ = 0 \), remains at equilibrium at all temperatures
  4. \( \Delta_r G^\circ < 0 \), nonspontaneous at high temperature

Correct answer · Option 1

\( \Delta_r G^\circ < 0 \), spontaneous at high temperature

Explanation

At high temperatures, \( T\Delta S^\circ > \Delta H^\circ \), making \( \Delta_r G^\circ \) negative, so the reaction is spontaneous.
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