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Chemistry · PYQ NEET UG 2020

हिन्दी

For the reaction, \( 2\mathrm{Cl}_{(\mathrm{g})} \longrightarrow \mathrm{Cl}_{2(\mathrm{g})} \), the correct option is _______.

  1. \( \Delta_{\mathrm{r}}H > 0 \) and \( \Delta_{\mathrm{r}}S < 0 \)
  2. \( \Delta_{\mathrm{r}}H < 0 \) and \( \Delta_{\mathrm{r}}S > 0 \)
  3. \( \Delta_{\mathrm{r}}H < 0 \) and \( \Delta_{\mathrm{r}}S < 0 \)
  4. \( \Delta_{\mathrm{r}}H > 0 \) and \( \Delta_{\mathrm{r}}S > 0 \)

Correct answer · Option 3

\( \Delta_{\mathrm{r}}H < 0 \) and \( \Delta_{\mathrm{r}}S < 0 \)

Explanation

Bond formation releases energy, so \( \Delta_r H < 0 \). Entropy decreases due to reduction in moles of gas, so \( \Delta_r S < 0 \).
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