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Chemistry · THERMODYNAMICS

हिन्दी

According to IUPAC and thermodynamic conventions, the standard molar enthalpy of formation (\( \Delta_f H^\ominus \)) at 298 K and 1 bar is non-zero for which of the following species?

  1. C(diamond)
  2. C(graphite)
  3. Br₂(l)
  4. O₂(g)

Correct answer · Option 1

C(diamond)

Explanation

The standard reference state of carbon is graphite, so \( \Delta_f H^\ominus[\text{C}(\text{graphite})] = 0 \), whereas \( \Delta_f H^\ominus[\text{C}(\text{diamond})] = +1.89\text{ kJ mol}^{-1} \neq 0 \).
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