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Chemistry · PYQ NEET UG 2016(2)

हिन्दी

The decomposition of phosphine (\( \text{PH}_3 \)) on tungsten at low pressure is a first order reaction. It is because the ______

  1. rate of decomposition is very slow
  2. rate is proportional to the surface coverage
  3. rate is inversely proportional to the surface coverage
  4. rate is independent of the surface coverage

Correct answer · Option 2

rate is proportional to the surface coverage

Explanation

At low pressures, adsorption is proportional to pressure, making the surface coverage \( \theta \) small, so the rate depends linearly on \( \theta \) (first order).
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