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Chemistry · PYQ NEET UG 2016(1)

हिन्दी

Consider the following liquid-vapour equilibrium. \( \text{Liquid} \rightleftharpoons \text{Vapour} \) Which of the following relation is correct?

  1. \( \frac{\mathrm{d}\ln P}{\mathrm{d}T} = \frac{-\Delta H_v}{T^2} \)
  2. \( \frac{\mathrm{d}\ln P}{\mathrm{d}T} = \frac{\Delta H_v}{RT^2} \)
  3. \( \frac{\mathrm{d}\ln G}{\mathrm{d}T} = \frac{\Delta H_v}{RT^2} \)
  4. \( \frac{\mathrm{d}\ln P}{\mathrm{d}T} = \frac{-\Delta H_v}{RT} \)

Correct answer · Option 2

\( \frac{\mathrm{d}\ln P}{\mathrm{d}T} = \frac{\Delta H_v}{RT^2} \)

Explanation

According to the Clausius-Clapeyron equation, \( \frac{\mathrm{d}\ln P}{\mathrm{d}T} = \frac{\Delta H_v}{RT^2} \).
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