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Chemistry · THERMODYNAMICS

हिन्दी

Refer to the given enthalpy diagrams Fig. 5.10 (a) and Fig. 5.10 (b). Which of the following statements correctly differentiates the two diagrams?

  1. In (a), \( \Delta_r H < 0 \) (net heat evolved, exothermic); in (b), \( \Delta_r H > 0 \) (net heat absorbed, endothermic).
  2. Both (a) and (b) represent endothermic reactions at different temperatures.
  3. Diagram (a) represents an endothermic process whereas diagram (b) represents an exothermic process.
  4. In (a), \( H_{\text{products}} > H_{\text{reactants}} \) and heat is absorbed; in (b), \( H_{\text{products}} < H_{\text{reactants}} \) and heat is evolved.

Correct answer · Option 1

In (a), \( \Delta_r H < 0 \) (net heat evolved, exothermic); in (b), \( \Delta_r H > 0 \) (net heat absorbed, endothermic).

Explanation

Fig 5.10(a) shows reactants at higher enthalpy than products (\( \Delta_r H < 0 \), exothermic), whereas Fig 5.10(b) shows products at higher enthalpy than reactants (\( \Delta_r H > 0 \), endothermic).
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