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Chemistry · THERMODYNAMICS

हिन्दी

For an irreversible isothermal expansion of an ideal gas, which of the following conditions correctly describes \( \Delta U \) and \( \Delta S_{\text{total}} \)?

  1. A
    \( \Delta U = 0 \) and \( \Delta S_{\text{total}} > 0 \)
  2. B
    \( \Delta U = 0 \) and \( \Delta S_{\text{total}} = 0 \)
  3. C
    \( \Delta U \neq 0 \) and \( \Delta S_{\text{total}} = 0 \)
  4. D
    \( \Delta U > 0 \) and \( \Delta S_{\text{total}} < 0 \)
View Answer & Solution

Correct answer · Option A

\( \Delta U = 0 \) and \( \Delta S_{\text{total}} > 0 \)

Explanation

For an isothermal expansion of an ideal gas, \( \Delta U = 0 \), but for an irreversible process, \( \Delta S_{\text{total}} = \Delta S_{\text{sys}} + \Delta S_{\text{surr}} > 0 \).
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