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Chemistry · THERMODYNAMICS

हिन्दी

For most ionic compounds, the enthalpy of solution (\( \Delta_{\text{sol}} H^\ominus \)) is positive, yet they dissolve in water. Why does the solubility of most such salts increase with a rise in temperature?

  1. A
    Because hydration enthalpy becomes infinitely negative at elevated temperatures.
  2. B
    Because the dissolution is endothermic, and according to Le Chatelier's principle, an increase in temperature shifts the equilibrium towards dissolution.
  3. C
    Because lattice enthalpy decreases to zero at higher temperatures.
  4. D
    Because ionic radius of cations decreases upon heating, decreasing the hydration shell.
View Answer & Solution

Correct answer · Option B

Because the dissolution is endothermic, and according to Le Chatelier's principle, an increase in temperature shifts the equilibrium towards dissolution.

Explanation

Since \( \Delta_{\text{sol}} H^\ominus > 0 \), the dissolution process is endothermic; hence, supplying heat (increasing temperature) favors dissolution according to Le Chatelier's principle.
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