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Chemistry · Classification of Elements and Periodicity in Properties

हिन्दी

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): The first ionization enthalpy of molecular nitrogen is greater than that of oxygen. Reason (R): Nitrogen has a stable half-filled \( 2p^3 \) electronic configuration which requires higher energy to remove an electron compared to oxygen's \( 2p^4 \) configuration. In the light of the above statements, choose the correct answer from the options given below:

  1. A
    Both (A) and (R) are true and (R) is the correct explanation of (A).
  2. B
    Both (A) and (R) are true but (R) is NOT the correct explanation of (A).
  3. C
    (A) is true but (R) is false.
  4. D
    (A) is false but (R) is true.
View Answer & Solution

Correct answer · Option A

Both (A) and (R) are true and (R) is the correct explanation of (A).

Explanation

Nitrogen (\( 1s^2 2s^2 2p^3 \)) has extra stability due to its half-filled p-orbitals, leading to a higher ionization enthalpy than oxygen (\( 1s^2 2s^2 2p^4 \)). Thus both Assertion and Reason are true and R correctly explains A.
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