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Chemistry · CHEMICAL BONDING AND MOLECULAR STRUCTURE

हिन्दी

In terms of orbital overlap and bond directionality, which statement explains why simple atomic orbital overlap fails to describe the geometry of \( \text{CH}_4 \)?

  1. A
    Carbon has only two valence electrons available for bonding in its ground state
  2. B
    Carbon forms ionic bonds rather than covalent directional bonds with hydrogen
  3. C
    The \( 2s \) orbital of carbon cannot overlap with the spherical \( 1s \) orbital of hydrogen
  4. D
    The mutual \( 90^\circ \) angles between the three \( 2p \) orbitals would predict \( 90^\circ \) bond angles rather than the observed \( 109.5^\circ \)

Correct answer · Option D

The mutual \( 90^\circ \) angles between the three \( 2p \) orbitals would predict \( 90^\circ \) bond angles rather than the observed \( 109.5^\circ \)

Explanation

Pure 2p orbitals are mutually perpendicular at 90°, so pure p-orbital overlap would lead to 90° H-C-H angles, contradicting the tetrahedral 109.5° angle.
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