Chemistry · CHEMICAL BONDING AND MOLECULAR STRUCTURE
हिन्दीIn terms of orbital overlap and bond directionality, which statement explains why simple atomic orbital overlap fails to describe the geometry of \( \text{CH}_4 \)?
Correct answer · Option D
The mutual \( 90^\circ \) angles between the three \( 2p \) orbitals would predict \( 90^\circ \) bond angles rather than the observed \( 109.5^\circ \)
Explanation
Pure 2p orbitals are mutually perpendicular at 90°, so pure p-orbital overlap would lead to 90° H-C-H angles, contradicting the tetrahedral 109.5° angle.