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Chemistry · PYQ NEET UG 2025

हिन्दी

The correct order of the wavelength of light absorbed by the following complexes is, A. \( [\mathrm{Co}(\mathrm{NH}_3)_6]^{3+} \) B. \( [\mathrm{Co}(\mathrm{CN})_6]^{3-} \) C. \( [\mathrm{Cu}(\mathrm{H}_2\mathrm{O})_4]^{2+} \) D. \( [\mathrm{Ti}(\mathrm{H}_2\mathrm{O})_6]^{3+} \) Choose the correct answer from the options given below:

  1. A
    B < D < A < C
  2. B
    B < A < D < C
  3. C
    C < D < A < B
  4. D
    C < A < D < B
View Answer & Solution

Correct answer · Option A

B < D < A < C

Explanation

Wavelength \( \lambda \) is inversely proportional to crystal field splitting energy \( \Delta_0 \). Stronger field ligand \( (\mathrm{CN}^- > \mathrm{NH}_3 > \mathrm{H}_2\mathrm{O}) \) gives larger \( \Delta_0 \) and hence shorter wavelength.
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