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Chemistry · CHEMICAL BONDING AND MOLECULAR STRUCTURE

हिन्दी

The ground state electronic configuration of the central nitrogen atom in \( \text{NH}_3 \) is \( 2s^2 2p_x^1 2p_y^1 2p_z^1 \). The observed \( \text{H}-\text{N}-\text{H} \) bond angle is reduced from \( 109.5^\circ \) to \( 107^\circ \) primarily because:

  1. A
    Bond pair-bond pair repulsion is stronger than lone pair-bond pair repulsion
  2. B
    Lone pair-bond pair repulsion is greater than bond pair-bond pair repulsion
  3. C
    Nitrogen undergoes \( sp^2 \) hybridisation instead of \( sp^3 \)
  4. D
    Hydrogen atoms attract each other
View Answer & Solution

Correct answer · Option B

Lone pair-bond pair repulsion is greater than bond pair-bond pair repulsion

Explanation

The repulsion between the lone pair and bond pairs is greater than that between bond pairs, causing the bond angle to decrease from \( 109.5^\circ \) to \( 107^\circ \).
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