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Physics · JEE | THERMODYNAMICS

हिन्दी

The heat capacity change \( \Delta_r C_p \) for a reaction at constant pressure is related to temperature dependence of reaction enthalpy via Kirchhoff's equation. For an ionization reaction, if \( C_p = \frac{5}{2}R \), the molar heat capacity contribution is:

  1. A
    \( \frac{3}{2}R \)
  2. B
    \( -\frac{5}{2}R \)
  3. C
    \( \frac{5}{2}R \)
  4. D
    \( -\frac{3}{2}R \)
View Answer & Solution

Correct answer · Option C

\( \frac{5}{2}R \)

Explanation

For ionization, the heat capacity change contributes +\frac{5}{2}R as derived from translational and internal degrees of freedom in the Born-Haber analysis box.
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