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Chemistry · CHEMICAL BONDING AND MOLECULAR STRUCTURE

हिन्दी

What is the primary factor that makes a \( \sigma \) bond stronger than a \( \pi \) bond formed between the same two atoms?

  1. A
    Axial head-on overlap permits a larger extent of orbital overlapping along the internuclear axis
  2. B
    Sidewise overlap provides greater electron density above and below the internuclear axis
  3. C
    A \( \sigma \) bond involves only pure \( s \)-orbitals whereas a \( \pi \) bond involves \( d \)-orbitals
  4. D
    A \( \pi \) bond is formed before the \( \sigma \) bond and repels approaching nuclei
View Answer & Solution

Correct answer · Option A

Axial head-on overlap permits a larger extent of orbital overlapping along the internuclear axis

Explanation

The strength of a covalent bond depends on the extent of overlap; axial (head-on) overlap for a sigma bond occurs to a much greater extent than lateral overlap for a pi bond.
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