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Chemistry · THERMODYNAMICS

हिन्दी

Which of the following chemical reactions is endothermic yet known to proceed spontaneously under appropriate conditions?

  1. A
    \( \text{C}(\text{graphite}) + 2\text{S}(\text{l}) \rightarrow \text{CS}_2(\text{l}) \)
  2. B
    \( \frac{1}{2}\text{N}_2(\text{g}) + \frac{3}{2}\text{H}_2(\text{g}) \rightarrow \text{NH}_3(\text{g}) \)
  3. C
    \( \frac{1}{2}\text{H}_2(\text{g}) + \frac{1}{2}\text{Cl}_2(\text{g}) \rightarrow \text{HCl}(\text{g}) \)
  4. D
    \( \text{H}_2(\text{g}) + \frac{1}{2}\text{O}_2(\text{g}) \rightarrow \text{H}_2\text{O}(\text{l}) \)
View Answer & Solution

Correct answer · Option A

\( \text{C}(\text{graphite}) + 2\text{S}(\text{l}) \rightarrow \text{CS}_2(\text{l}) \)

Explanation

\( \text{C}(\text{graphite}) + 2\text{S}(\text{l}) \rightarrow \text{CS}_2(\text{l}) \) has \( \Delta_r H^\ominus = +128.5\text{ kJ mol}^{-1} \), an endothermic reaction showing that decrease in enthalpy is not the sole criterion for spontaneity.
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