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Chemistry · PYQ NEET UG 2016(2)

हिन्दी

Which one of the following nitro compounds does NOT react with nitrous acid?

  1. A
    \( \text{H}_3\text{C}-\text{C}-\text{CH}-\text{NO}_2 \) (where \( \text{C}=\text{O} \) is attached)
  2. B
    \( \text{H}_3\text{C}-\text{CH}_2-\text{CH}_2-\text{NO}_2 \)
  3. C
    \( \text{H}_3\text{C}-\text{CH}-\text{CH}_2-\text{NO}_2 \) (with \( \text{CH}_3 \) at C2)
  4. D
    \( \text{H}_3\text{C}-\text{C}(\text{CH}_3)_2-\text{NO}_2 \)

Correct answer · Option D

\( \text{H}_3\text{C}-\text{C}(\text{CH}_3)_2-\text{NO}_2 \)

Explanation

Tertiary nitroalkanes (like \( \text{R}_3\text{C}-\text{NO}_2 \)) do not have \( \alpha \)-hydrogen atoms, hence they do not react with nitrous acid.
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