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Chemistry · CHEMICAL BONDING AND MOLECULAR STRUCTURE

हिन्दी

Why is hybridization involving \( 3p \), \( 3d \), and \( 4s \) orbitals not possible in third-period elements, despite the energy of \( 3d \) orbitals being comparable to both \( 3s, 3p \) and \( 4s, 4p \)?

  1. A
    Because the \( 3d \) orbitals have too high azimuthal quantum numbers
  2. B
    Because electron promotion from \( 3p \) directly into \( 4s \) is spin-forbidden
  3. C
    Because \( 4s \) orbitals cannot participate in any hybridization scheme
  4. D
    Because the difference in energies of \( 3p \) and \( 4s \) orbitals is significant
View Answer & Solution

Correct answer · Option D

Because the difference in energies of \( 3p \) and \( 4s \) orbitals is significant

Explanation

Hybridization requires participating orbitals to have comparable energies; the large energy gap between 3p and 4s prevents their simultaneous hybridization with 3d.
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