Chemistry · THERMODYNAMICS
हिन्दीWhy is it impossible to determine the lattice enthalpy of an ionic crystal like \( \text{NaCl}(s) \) directly by experiment?
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Correct answer · Option A
Because an isolated ionic solid cannot be vaporized directly into separated gaseous ions without supplying high thermal energy that triggers non-ionic decomposition.
Explanation
Direct experimental separation of an ionic solid into separated gaseous ions at standard conditions cannot be performed directly; an indirect Born-Haber cycle using Hess's Law is required.