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Chemistry · THERMODYNAMICS

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Why is it impossible to determine the lattice enthalpy of an ionic crystal like \( \text{NaCl}(s) \) directly by experiment?

  1. A
    Because an isolated ionic solid cannot be vaporized directly into separated gaseous ions without supplying high thermal energy that triggers non-ionic decomposition.
  2. B
    Because standard states of sodium and chlorine are not gases under normal conditions.
  3. C
    Because the gaseous ions immediately condense back into solid before thermal changes can be measured.
  4. D
    Because the process involves non-stoichiometric electronic transitions.
View Answer & Solution

Correct answer · Option A

Because an isolated ionic solid cannot be vaporized directly into separated gaseous ions without supplying high thermal energy that triggers non-ionic decomposition.

Explanation

Direct experimental separation of an ionic solid into separated gaseous ions at standard conditions cannot be performed directly; an indirect Born-Haber cycle using Hess's Law is required.
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